{"created":"2025-04-10T02:13:21.039707+00:00","id":2001145,"links":{},"metadata":{"_buckets":{"deposit":"63f9fcf4-48be-47c7-b85b-dba40ba2f76a"},"_deposit":{"created_by":10,"id":"2001145","owners":[10],"pid":{"revision_id":0,"type":"depid","value":"2001145"},"status":"published"},"_oai":{"id":"oai:senshu-u.repo.nii.ac.jp:02001145","sets":["27:32:162:163:1744250764920"]},"author_link":[],"control_number":"2001145","item_10002_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2025-03-15","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"49","bibliographicPageStart":"45","bibliographicVolumeNumber":"56","bibliographic_titles":[{"bibliographic_title":"専修自然科学紀要","bibliographic_titleLang":"ja"}]}]},"item_10002_creator_2":{"attribute_name":"作成者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"Matsumoto, Kouzou","creatorNameLang":"en","creatorNameType":"Personal"},{"creatorName":"松本, 幸三","creatorNameLang":"ja","creatorNameType":"Personal"}]},{"creatorNames":[{"creatorName":"Kurata, Hiroyuki","creatorNameLang":"en","creatorNameType":"Personal"},{"creatorName":"蔵田, 浩之","creatorNameLang":"ja","creatorNameType":"Personal"}]}]},"item_10002_description_25":{"attribute_name":"内容記述","attribute_value_mlt":[{"subitem_description":"The reaction of 2-chloropyrazine with 0.5 equivalent of lithium diisopropylamide (LDA) was examined. Although we expected 3-chloro-2,2'-bipyrazine as the main product, 3,3'-dichloro-2,2'-bipyrazine was obtained in low yield (7%). The reaction was not clean and considerable amount of intractable precipitates and several byproducts were formed. Among them, 3,3',3'''-trichloro-2,2':5',2'':6'',2'''-quarterpyrazine was isolated and unambiguously identified by X-ray crystallographic analysis.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_10002_identifier_registration":{"attribute_name":"identifier_registration","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.34360/0002001145","subitem_identifier_reg_type":"JaLC"}]},"item_10002_publisher_26":{"attribute_name":"公開者","attribute_value_mlt":[{"subitem_publisher":"専修大学自然科学研究所","subitem_publisher_language":"ja"}]},"item_10002_source_id_28":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0386-5827","subitem_source_identifier_type":"PISSN"}]},"item_10002_source_id_29":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00132417","subitem_source_identifier_type":"NCID"}]},"item_10002_version_type_20":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_970fb48d4fbd8a85","subitem_version_type":"VoR"}]},"item_access_right":{"attribute_name":"アクセス権","attribute_value_mlt":[{"subitem_access_right":"open access","subitem_access_right_uri":"http://purl.org/coar/access_right/c_abf2"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","displaytype":"detail","filename":"3102_0056_05.pdf","filesize":[{"value":"598.6 KB"}],"format":"application/pdf","license_note":"著作権法の規定の範囲(私的利用、引用など)を超えて利用する場合には、著作権者の許諾が必要です。","licensetype":"license_note","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://senshu-u.repo.nii.ac.jp/record/2001145/files/3102_0056_05.pdf"},"version_id":"99128da2-fda8-48f3-b50c-47fd3a2fd3ce"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"item_resource_type","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Synthesis of 3,3'-Dichloro-2,2'-bipyrazine","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Synthesis of 3,3'-Dichloro-2,2'-bipyrazine","subitem_title_language":"en"}]},"item_type_id":"10002","owner":"10","path":["1744250764920"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2025-04-10"},"publish_date":"2025-04-10","publish_status":"0","recid":"2001145","relation_version_is_last":true,"title":["Synthesis of 3,3'-Dichloro-2,2'-bipyrazine"],"weko_creator_id":"10","weko_shared_id":-1},"updated":"2025-04-10T02:39:28.460269+00:00"}